Place the finely chopped chocolate in a heatproof bowl.
In a small saucepan, warm the heavy cream over medium heat until it just begins to simmer—avoid boiling. Once the cream reaches a simmer, pour it over the chocolate. Let the mixture sit undisturbed for several minutes, allowing the chocolate to soften.
Using a spatula, gently stir the chocolate and cream together. At first, it may look like the mixture won't combine, but keep stirring until it transforms into a smooth, glossy ganache. Allow it to cool for about 15 minutes to thicken slightly.
Once the ganache has cooled a bit, slowly pour it over the top of the cooled cake. Use a spatula to spread it evenly, allowing it to cascade gently down the sides for an elegant finish.