Preheat your oven to 325°F (165°C). Prepare three 8×2 inch round cake pans by greasing them with vegetable shortening and lightly flouring them. Place parchment circles on the bottoms for added ease of removal.
In a medium mixing bowl, combine the flour, cocoa powder, baking powder, baking soda, and salt. Whisk these dry ingredients together thoroughly and set aside.
In a separate bowl, blend the buttermilk, vegetable oil, and vanilla extract. Set this wet mixture aside.
In the bowl of your stand mixer, beat the softened butter on medium speed until it becomes smooth and creamy. Gradually add the sugar, continuing to mix for 3-5 minutes until the mixture is fluffy and light in color.
Incorporate the eggs one at a time, mixing well after each addition until the yolks are fully blended into the batter.
On low speed, begin adding the dry ingredients alternately with the buttermilk mixture, starting and ending with the dry ingredients (three additions of dry ingredients and two of wet). Mix just until everything is well incorporated.
Keeping the mixer on low, gradually pour in the hot coffee, blending until the batter is smooth and well mixed.
Evenly distribute the batter among the three prepared cake pans. Bake in the preheated oven for 25-30 minutes or until a toothpick inserted into the center comes out clean or with a few moist crumbs. Allow the cakes to cool in the pans for 5-10 minutes before turning them out onto a wire rack.