Preheat your oven to 350°F (177°C). Prepare three 8-inch round cake pans by greasing and flouring them; lining the bottoms with parchment paper is also recommended for easy removal.
In the mixing bowl, combine the dry ingredients: flour, cocoa powder, granulated sugar, baking powder, baking soda, salt, and instant espresso granules. Whisk together until well-blended.
Add the eggs, vegetable oil, vanilla extract, and ¼ cup of the hot water to the dry ingredients. Mix on medium speed for about 2 minutes, ensuring you scrape down the sides of the bowl occasionally, as the batter will be thick.
With the mixer set to low, gradually pour in the remaining 1 cup of very hot water. Continue mixing for about 30 seconds until fully combined; the batter will become thin.
Divide the batter evenly among the three prepared cake pans. Lightly tap each pan on the countertop a few times to release any air bubbles.
Bake for 22-24 minutes or until a wooden skewer or toothpick inserted into the center comes out clean or with just a few moist crumbs attached. Allow the cake layers to cool in their pans on a wire rack for 10 minutes before gently turning them out to cool completely.