Begin by preheating your oven to 325°F (163°C). Grease and flour three 8-inch round cake pans, lining the bottoms with parchment paper if desired for easier release.
In a mixing bowl, combine the Devil’s Food cake mix, flour, sugar, and dry pudding mix, stirring to ensure all dry ingredients are evenly distributed.
Add sour cream, vegetable oil, water, eggs, and vanilla extract to the bowl. Start mixing at a low speed for 30 seconds, then increase to medium speed for 2 minutes, stopping to scrape the bowl as needed. The batter should be smooth and well-blended.
Divide the batter evenly among the prepared cake pans. Bake for 20-25 minutes, checking for doneness by lightly pressing the top to see if it springs back or inserting a toothpick that comes out with a few moist crumbs. Remember that dark pans may reduce the baking time slightly.
Once done, let the cakes cool in their pans on a wire rack for about 10 minutes, then carefully turn them out to cool completely before frosting.