Prepare two 6-inch round cake pans by lining the bottoms with parchment paper. Lightly grease the sides for an easy release. Set the pans aside.
Preheat your oven to 325°F (163°C).
In the bowl of a stand mixer fitted with the paddle attachment, sift together the flour, cocoa powder, sugar, baking powder, baking soda, and sea salt. Mix briefly to combine.
In a separate measuring cup, combine the avocado oil, buttermilk, hot boiling water, and vanilla extract. Stir gently to ensure all liquids are incorporated.
With the mixer on low speed, slowly pour the wet ingredients into the dry mixture. Allow the mixer to run for about 30 seconds, just until the batter turns smooth. Avoid overmixing.
Scrape down the sides of the bowl with a spatula. With the mixer still on low, add the eggs, one at a time. After each egg, mix until the batter is silky and evenly combined, about 30-60 seconds.
Divide the batter evenly between the two prepared cake pans. Tap each pan firmly on the counter a few times to release any air bubbles trapped in the batter.
Bake in the preheated oven for 30-35 minutes, or until a toothpick inserted in the center comes out clean with only a few moist crumbs.
Remove the cakes from the oven and allow them to cool for about 15 minutes while still in their pans. Gently run a knife along the edges and carefully invert each cake onto a cooling rack to cool completely.