In a large mixing bowl, whisk together the flour, cocoa, sugar, baking powder, baking soda, and salt. In a separate bowl, beat together the eggs, buttermilk, oil, and vanilla extract. Gradually add the wet ingredients into the dry mixture, stirring until combined. Carefully pour in the boiling water and stir—the batter will become quite thin. Divide the batter evenly between the prepared cake pans.